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石墨相氮化碳基光催化剂改性研究的进展

黄明秀,  王贝

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文章导航 > 热带生物学报  > 2024 >  15(4): 499-508
黄明秀, 王贝. 石墨相氮化碳基光催化剂改性研究的进展[J]. 热带生物学报, 2024, 15(4): 499-508. doi: 10.15886/j.cnki.rdswxb.20230111
引用本文: 黄明秀, 王贝. 石墨相氮化碳基光催化剂改性研究的进展[J]. 热带生物学报, 2024, 15(4): 499-508. doi: 10.15886/j.cnki.rdswxb.20230111
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HUANG Mingxiu, WANG Bei. Advances in research of the modification of graphitic carbon nitride based photocatalysts[J]. Journal of Tropical Biology, 2024, 15(4): 499-508. doi: 10.15886/j.cnki.rdswxb.20230111
Citation: HUANG Mingxiu, WANG Bei. Advances in research of the modification of graphitic carbon nitride based photocatalysts[J]. Journal of Tropical Biology, 2024, 15(4): 499-508. doi: 10.15886/j.cnki.rdswxb.20230111
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石墨相氮化碳基光催化剂改性研究的进展

doi: 10.15886/j.cnki.rdswxb.20230111

  • 海南师范大学 化学与化工学院/海南省激光技术与光电功能材料重点实验室/海口市功能材料与光电化学重点实验室, 海口 571158

基金项目: 

海南省自然科学基金资助项目(521QN238)

详细信息
    第一作者:

    黄明秀(2000-),女,海南师范大学化学与化工学院2022级硕士研究。E-mail:1939951811@qq.com

    通信作者:

    王贝(1992-),女,讲师,博士。研究方向:光电功能材料与器件。E-mail:beiwang_31@163.com

  • 中图分类号: TG142.1

Advances in research of the modification of graphitic carbon nitride based photocatalysts

  • Hainan Key Laboratory of Laser Technology and Photoelectric Functional Materials/Haikou Key Laboratory of Functional Materials and Photoelectric Chemistry, School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou, Hainan 571158, China

  • 摘要: 光催化剂能够利用太阳能转化为化学能，在污染物降解、光解水产氢、二氧化碳还原等方面显示出巨大的应用潜力。作为一种新型光催化剂，石墨相氮化碳（g-C3N4）具有诸多优异的特性，低廉的制备成本、可调节的光学带隙、出色的化学与物理稳定性等，引起了研究人员的广泛关注。但未修饰的g-C3N4存在比表面积小，反应的活性位点不足，量子效率低和光生电荷载流子复合率较高等缺点，限制了g-C3N4在光催化领域中的应用，故而对现有的g-C3N4光催化剂进行改性，以改善其光催化性能。结合氮化碳改性处理迄今已取得显著成果，作者综述了石墨相氮化碳复合材料的主要改性方法，包括：元素掺杂、缺陷工程、设计各类纳米结构和构建异质结等，并对g-C3N4在光催化领域的发展趋势进行了展望，以供研究者参考。
    Abstract: Photocatalysts can convert solar energy into chemical energy and show great potential for applications in pollutant degradation, hydrogen production by water photolysis, and CO2 reduction. As one of the new photocatalysts, graphitic carbon nitride（g-C3N4） has many excellent properties, low preparation cost, adjustable optical band gap, excellent chemical and physical stability, etc., which have attracted a lot of attention from researchers. However, the unmodified g-C3N4 suffers from small specific surface area, insufficient active sites for reaction, low quantum efficiency and high complexation rate of photogenerated charge carriers, which limit the application of g-C3N4 in photocatalysis. Therefore, the existing g-C3N4 photocatalysts are modified to improve their photocatalytic performance. Combined with the remarkable results achieved so far in carbon nitride modification treatment, the authors review the main methods for modification of graphite-phase carbon nitride composites,including elemental doping, defect engineering, design of various nanostructures and construction of heterojunctions, and make an outlook on the development trend of g-C3N4 in photocatalysis for reference.
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  • [1] 林德鑫, 衣雪松.  FeCl3改性活性炭的制备、表征与吸附性能研究 . 热带生物学报, 2023, 14(4): 371-378. doi: 10.15886/j.cnki.rdswxb.2023.04.004
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    • 收稿日期:  2023-09-16
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    石墨相氮化碳基光催化剂改性研究的进展

    doi: 10.15886/j.cnki.rdswxb.20230111
    • 海南师范大学 化学与化工学院/海南省激光技术与光电功能材料重点实验室/海口市功能材料与光电化学重点实验室, 海口 571158
      • 基金项目:

      海南省自然科学基金资助项目(521QN238)

      作者简介:

      黄明秀(2000-),女,海南师范大学化学与化工学院2022级硕士研究。E-mail:1939951811@qq.com

      通讯作者: 王贝(1992-),女,讲师,博士。研究方向:光电功能材料与器件。E-mail:beiwang_31@163.com
    • 收稿日期: 2023-09-16
    • 修回日期: 2023-10-31
    • 刊出日期: 2024-07-25

    • 中图分类号: TG142.1

    摘要: 光催化剂能够利用太阳能转化为化学能，在污染物降解、光解水产氢、二氧化碳还原等方面显示出巨大的应用潜力。作为一种新型光催化剂，石墨相氮化碳（g-C3N4）具有诸多优异的特性，低廉的制备成本、可调节的光学带隙、出色的化学与物理稳定性等，引起了研究人员的广泛关注。但未修饰的g-C3N4存在比表面积小，反应的活性位点不足，量子效率低和光生电荷载流子复合率较高等缺点，限制了g-C3N4在光催化领域中的应用，故而对现有的g-C3N4光催化剂进行改性，以改善其光催化性能。结合氮化碳改性处理迄今已取得显著成果，作者综述了石墨相氮化碳复合材料的主要改性方法，包括：元素掺杂、缺陷工程、设计各类纳米结构和构建异质结等，并对g-C3N4在光催化领域的发展趋势进行了展望，以供研究者参考。

    English Abstract

    黄明秀, 王贝. 石墨相氮化碳基光催化剂改性研究的进展[J]. 热带生物学报, 2024, 15(4): 499-508. doi: 10.15886/j.cnki.rdswxb.20230111
    引用本文: 黄明秀, 王贝. 石墨相氮化碳基光催化剂改性研究的进展[J]. 热带生物学报, 2024, 15(4): 499-508. doi: 10.15886/j.cnki.rdswxb.20230111
    shu
    HUANG Mingxiu, WANG Bei. Advances in research of the modification of graphitic carbon nitride based photocatalysts[J]. Journal of Tropical Biology, 2024, 15(4): 499-508. doi: 10.15886/j.cnki.rdswxb.20230111
    Citation: HUANG Mingxiu, WANG Bei. Advances in research of the modification of graphitic carbon nitride based photocatalysts[J]. Journal of Tropical Biology, 2024, 15(4): 499-508. doi: 10.15886/j.cnki.rdswxb.20230111
    shu

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